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A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc(3)N@I(h)-C(80)(–))(2) dimers
Reduction of scandium nitride clusterfullerene, Sc(3)N@I(h)-C(80), by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na(+))}(2)(Sc(3)N@I(h)-C(80)(–))(2)·2.5C(6)H(4)Cl(2) (1) salt. The Sc(3)N@I(h)-C(80)˙(–) radical anions are dimerized to...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730043/ https://www.ncbi.nlm.nih.gov/pubmed/27511304 http://dx.doi.org/10.1039/c6cc05550h |