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Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate)
In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendicular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730230/ https://www.ncbi.nlm.nih.gov/pubmed/29250393 http://dx.doi.org/10.1107/S2056989017015730 |
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author | Li, Yu-Long Sun, Hong-Shun Jiang, Hong Chen, Yu-Liang Chen, Yang-Feng |
author_facet | Li, Yu-Long Sun, Hong-Shun Jiang, Hong Chen, Yu-Liang Chen, Yang-Feng |
author_sort | Li, Yu-Long |
collection | PubMed |
description | In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendicular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole ring systems by 76.1 (3) and 78.3 (4)°. Weak intramolecular C—H⋯π interactions affect the molecular conformation. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into inversion dimers which are further linked into supramolecular chains by N—H⋯O hydrogen bonds and short Cl—Cl contacts. |
format | Online Article Text |
id | pubmed-5730230 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-57302302017-12-15 Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) Li, Yu-Long Sun, Hong-Shun Jiang, Hong Chen, Yu-Liang Chen, Yang-Feng Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendicular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole ring systems by 76.1 (3) and 78.3 (4)°. Weak intramolecular C—H⋯π interactions affect the molecular conformation. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into inversion dimers which are further linked into supramolecular chains by N—H⋯O hydrogen bonds and short Cl—Cl contacts. International Union of Crystallography 2017-11-03 /pmc/articles/PMC5730230/ /pubmed/29250393 http://dx.doi.org/10.1107/S2056989017015730 Text en © Li et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Li, Yu-Long Sun, Hong-Shun Jiang, Hong Chen, Yu-Liang Chen, Yang-Feng Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title | Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_full | Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_fullStr | Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_full_unstemmed | Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_short | Crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1H-indole-2-carboxylate) |
title_sort | crystal structure of diethyl 3,3′-[(2,4-dichlorophenyl)methylidene]bis(1h-indole-2-carboxylate) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730230/ https://www.ncbi.nlm.nih.gov/pubmed/29250393 http://dx.doi.org/10.1107/S2056989017015730 |
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