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Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendic­ular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole...

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Autores principales: Li, Yu-Long, Sun, Hong-Shun, Jiang, Hong, Chen, Yu-Liang, Chen, Yang-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730230/
https://www.ncbi.nlm.nih.gov/pubmed/29250393
http://dx.doi.org/10.1107/S2056989017015730
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author Li, Yu-Long
Sun, Hong-Shun
Jiang, Hong
Chen, Yu-Liang
Chen, Yang-Feng
author_facet Li, Yu-Long
Sun, Hong-Shun
Jiang, Hong
Chen, Yu-Liang
Chen, Yang-Feng
author_sort Li, Yu-Long
collection PubMed
description In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendic­ular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole ring systems by 76.1 (3) and 78.3 (4)°. Weak intra­molecular C—H⋯π inter­actions affect the mol­ecular conformation. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers which are further linked into supra­molecular chains by N—H⋯O hydrogen bonds and short Cl—Cl contacts.
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spelling pubmed-57302302017-12-15 Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate) Li, Yu-Long Sun, Hong-Shun Jiang, Hong Chen, Yu-Liang Chen, Yang-Feng Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(29)H(24)Cl(2)N(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.1249 and 0.0075 Å) are approximately perpendic­ular to one another, with a dihedral angle of 80.9 (5)° between them. The benzene ring is inclined to the mean planes of the two indole ring systems by 76.1 (3) and 78.3 (4)°. Weak intra­molecular C—H⋯π inter­actions affect the mol­ecular conformation. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers which are further linked into supra­molecular chains by N—H⋯O hydrogen bonds and short Cl—Cl contacts. International Union of Crystallography 2017-11-03 /pmc/articles/PMC5730230/ /pubmed/29250393 http://dx.doi.org/10.1107/S2056989017015730 Text en © Li et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Li, Yu-Long
Sun, Hong-Shun
Jiang, Hong
Chen, Yu-Liang
Chen, Yang-Feng
Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title_full Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title_fullStr Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title_full_unstemmed Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title_short Crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1H-indole-2-carboxyl­ate)
title_sort crystal structure of diethyl 3,3′-[(2,4-di­chloro­phen­yl)methyl­idene]bis­(1h-indole-2-carboxyl­ate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730230/
https://www.ncbi.nlm.nih.gov/pubmed/29250393
http://dx.doi.org/10.1107/S2056989017015730
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