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Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]
The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis p...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730248/ https://www.ncbi.nlm.nih.gov/pubmed/29250411 http://dx.doi.org/10.1107/S2056989017016164 |
Sumario: | The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs(2)SO(4) structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those. |
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