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Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]

The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anti­cancer activity in rodent test systems and recently found to have anti­fungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis p...

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Detalles Bibliográficos
Autores principales: Bhadbhade, Mohan Madhav, Charlson, Alexander J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730248/
https://www.ncbi.nlm.nih.gov/pubmed/29250411
http://dx.doi.org/10.1107/S2056989017016164
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author Bhadbhade, Mohan Madhav
Charlson, Alexander J.
author_facet Bhadbhade, Mohan Madhav
Charlson, Alexander J.
author_sort Bhadbhade, Mohan Madhav
collection PubMed
description The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anti­cancer activity in rodent test systems and recently found to have anti­fungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs(2)SO(4) structure. X-ray crystal structures of only three di­chlorido­palladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.
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spelling pubmed-57302482017-12-15 Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)] Bhadbhade, Mohan Madhav Charlson, Alexander J. Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anti­cancer activity in rodent test systems and recently found to have anti­fungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs(2)SO(4) structure. X-ray crystal structures of only three di­chlorido­palladium(II)–amino acid complexes have been determined so far and the present paper describes one of those. International Union of Crystallography 2017-11-21 /pmc/articles/PMC5730248/ /pubmed/29250411 http://dx.doi.org/10.1107/S2056989017016164 Text en © Bhadbhade and Charlson 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Bhadbhade, Mohan Madhav
Charlson, Alexander J.
Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title_full Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title_fullStr Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title_full_unstemmed Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title_short Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(II)]
title_sort crystal structure of poly[[μ(3)-(s)-2-amino-3-hydroxy­propano­ato]-cis-di-μ-chlorido-caesium­palladium(ii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730248/
https://www.ncbi.nlm.nih.gov/pubmed/29250411
http://dx.doi.org/10.1107/S2056989017016164
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