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Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]
The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis p...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730248/ https://www.ncbi.nlm.nih.gov/pubmed/29250411 http://dx.doi.org/10.1107/S2056989017016164 |
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author | Bhadbhade, Mohan Madhav Charlson, Alexander J. |
author_facet | Bhadbhade, Mohan Madhav Charlson, Alexander J. |
author_sort | Bhadbhade, Mohan Madhav |
collection | PubMed |
description | The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs(2)SO(4) structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those. |
format | Online Article Text |
id | pubmed-5730248 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-57302482017-12-15 Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] Bhadbhade, Mohan Madhav Charlson, Alexander J. Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title compound, [CsPd(C(3)H(6)NO(3))Cl(2)](n), previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated l-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs(2)SO(4) structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those. International Union of Crystallography 2017-11-21 /pmc/articles/PMC5730248/ /pubmed/29250411 http://dx.doi.org/10.1107/S2056989017016164 Text en © Bhadbhade and Charlson 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Bhadbhade, Mohan Madhav Charlson, Alexander J. Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title | Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title_full | Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title_fullStr | Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title_full_unstemmed | Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title_short | Crystal structure of poly[[μ(3)-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)] |
title_sort | crystal structure of poly[[μ(3)-(s)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(ii)] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730248/ https://www.ncbi.nlm.nih.gov/pubmed/29250411 http://dx.doi.org/10.1107/S2056989017016164 |
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