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Crystal structure of a diaryl carbonate: 1,3-phenylene bis(phenyl carbonate)
The whole molecule of the title compound, C(20)H(14)O(6), is generated by mirror symmetry, the mirror bisecting the central benzene ring. The carbonate groups adopt an s-cis-s-cis conformation, with torsion angles of 58.7 (2) and 116.32 (15)°. The crystal structure of 1,3-phenylene bis(phenyl ca...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730257/ https://www.ncbi.nlm.nih.gov/pubmed/29250420 http://dx.doi.org/10.1107/S2056989017016772 |
| Sumario: | The whole molecule of the title compound, C(20)H(14)O(6), is generated by mirror symmetry, the mirror bisecting the central benzene ring. The carbonate groups adopt an s-cis-s-cis conformation, with torsion angles of 58.7 (2) and 116.32 (15)°. The crystal structure of 1,3-phenylene bis(phenyl carbonate) contains no strong hydrogen bonds, though weak C—H⋯O and offset π–π interactions are observed, forming layers parallel to the ac plane. |
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