Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)

The whole mol­ecule of the title compound, C(20)H(14)O(6), is generated by mirror symmetry, the mirror bis­ecting the central benzene ring. The carbonate groups adopt an s-cis-s-cis conformation, with torsion angles of 58.7 (2) and 116.32 (15)°. The crystal structure of 1,3-phenyl­ene bis­(phenyl ca...

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Detalles Bibliográficos
Autores principales: Solomos, Marina A., Bertke, Jeffery A., Swift, Jennifer A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730257/
https://www.ncbi.nlm.nih.gov/pubmed/29250420
http://dx.doi.org/10.1107/S2056989017016772
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author Solomos, Marina A.
Bertke, Jeffery A.
Swift, Jennifer A.
author_facet Solomos, Marina A.
Bertke, Jeffery A.
Swift, Jennifer A.
author_sort Solomos, Marina A.
collection PubMed
description The whole mol­ecule of the title compound, C(20)H(14)O(6), is generated by mirror symmetry, the mirror bis­ecting the central benzene ring. The carbonate groups adopt an s-cis-s-cis conformation, with torsion angles of 58.7 (2) and 116.32 (15)°. The crystal structure of 1,3-phenyl­ene bis­(phenyl carbonate) contains no strong hydrogen bonds, though weak C—H⋯O and offset π–π inter­actions are observed, forming layers parallel to the ac plane.
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spelling pubmed-57302572017-12-15 Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate) Solomos, Marina A. Bertke, Jeffery A. Swift, Jennifer A. Acta Crystallogr E Crystallogr Commun Research Communications The whole mol­ecule of the title compound, C(20)H(14)O(6), is generated by mirror symmetry, the mirror bis­ecting the central benzene ring. The carbonate groups adopt an s-cis-s-cis conformation, with torsion angles of 58.7 (2) and 116.32 (15)°. The crystal structure of 1,3-phenyl­ene bis­(phenyl carbonate) contains no strong hydrogen bonds, though weak C—H⋯O and offset π–π inter­actions are observed, forming layers parallel to the ac plane. International Union of Crystallography 2017-11-28 /pmc/articles/PMC5730257/ /pubmed/29250420 http://dx.doi.org/10.1107/S2056989017016772 Text en © Solomos et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Solomos, Marina A.
Bertke, Jeffery A.
Swift, Jennifer A.
Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title_full Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title_fullStr Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title_full_unstemmed Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title_short Crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
title_sort crystal structure of a di­aryl carbonate: 1,3-phenyl­ene bis­(phenyl carbonate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730257/
https://www.ncbi.nlm.nih.gov/pubmed/29250420
http://dx.doi.org/10.1107/S2056989017016772
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