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Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendic­ular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (...

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Autores principales: Sun, Hong-Shun, Li, Yu-Long, Jiang, Hong, Chen, Yu-Liang, Hu, Ya-Di
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730260/
https://www.ncbi.nlm.nih.gov/pubmed/29250423
http://dx.doi.org/10.1107/S2056989017016929
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author Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Chen, Yu-Liang
Hu, Ya-Di
author_facet Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Chen, Yu-Liang
Hu, Ya-Di
author_sort Sun, Hong-Shun
collection PubMed
description In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendic­ular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (4) and 88.2 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into the inversion dimers, which are further linked into supra­molecular chains along the b-axis direction. Weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions are also observed in the crystal.
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spelling pubmed-57302602017-12-15 Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) Sun, Hong-Shun Li, Yu-Long Jiang, Hong Chen, Yu-Liang Hu, Ya-Di Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendic­ular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (4) and 88.2 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into the inversion dimers, which are further linked into supra­molecular chains along the b-axis direction. Weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions are also observed in the crystal. International Union of Crystallography 2017-11-28 /pmc/articles/PMC5730260/ /pubmed/29250423 http://dx.doi.org/10.1107/S2056989017016929 Text en © Sun et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Chen, Yu-Liang
Hu, Ya-Di
Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_fullStr Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full_unstemmed Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_short Crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_sort crystal structure of diethyl 3,3′-[(4-nitro­phen­yl)methyl­ene]bis­(1h-indole-2-carboxyl­ate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730260/
https://www.ncbi.nlm.nih.gov/pubmed/29250423
http://dx.doi.org/10.1107/S2056989017016929
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