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Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate)
In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendicular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730260/ https://www.ncbi.nlm.nih.gov/pubmed/29250423 http://dx.doi.org/10.1107/S2056989017016929 |
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author | Sun, Hong-Shun Li, Yu-Long Jiang, Hong Chen, Yu-Liang Hu, Ya-Di |
author_facet | Sun, Hong-Shun Li, Yu-Long Jiang, Hong Chen, Yu-Liang Hu, Ya-Di |
author_sort | Sun, Hong-Shun |
collection | PubMed |
description | In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendicular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (4) and 88.2 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into the inversion dimers, which are further linked into supramolecular chains along the b-axis direction. Weak C—H⋯O hydrogen bonds and C—H⋯π interactions are also observed in the crystal. |
format | Online Article Text |
id | pubmed-5730260 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-57302602017-12-15 Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) Sun, Hong-Shun Li, Yu-Long Jiang, Hong Chen, Yu-Liang Hu, Ya-Di Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(29)H(25)N(3)O(6), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0115 and 0.0082 Å) are approximately perpendicular to one another, making a dihedral angle of 89.7 (5)°; the benzene ring is twisted with respect to the two indole ring systems by 52.6 (4) and 88.2 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into the inversion dimers, which are further linked into supramolecular chains along the b-axis direction. Weak C—H⋯O hydrogen bonds and C—H⋯π interactions are also observed in the crystal. International Union of Crystallography 2017-11-28 /pmc/articles/PMC5730260/ /pubmed/29250423 http://dx.doi.org/10.1107/S2056989017016929 Text en © Sun et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Sun, Hong-Shun Li, Yu-Long Jiang, Hong Chen, Yu-Liang Hu, Ya-Di Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title | Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full | Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_fullStr | Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full_unstemmed | Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_short | Crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_sort | crystal structure of diethyl 3,3′-[(4-nitrophenyl)methylene]bis(1h-indole-2-carboxylate) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730260/ https://www.ncbi.nlm.nih.gov/pubmed/29250423 http://dx.doi.org/10.1107/S2056989017016929 |
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