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Unusual formation of (E)-11-(amino­methyl­ene)-8,9,10,11-tetra­hydro­pyrido[2′,3′:4,5]pyrimido[1,2-a]azepin-5(7H)-one and its crystal structure

Selective C-formyl­ation of 8,9,10,11-tetra­hydro­pyrido[2′,3′:4,5]pyrimido[1,2-a]-azepin-5(7H)-one has been studied for the first time. It was revealed that formyl­ation proceeds by the formation of an inter­mediate salt, which due to the re-amination process on treatment with aqueous ammonia trans...

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Detalles Bibliográficos
Autores principales: Khodjaniyazov, Khamid U., Makhmudov, Utkir S., Turgunov, Kambarali K., Elmuradov, Burkhon Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730303/
https://www.ncbi.nlm.nih.gov/pubmed/29250366
http://dx.doi.org/10.1107/S2056989017013093

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