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Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide

In the title compound, C(14)H(18)N(2)O(2)S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth­oxy­benzoyl ring, with a dihedral angle of 63.0 (3)°. The central N—C(=S)—N(H)—C(=O) bridge is twisted with an N—C—N—C torsion angle of 74.8 (6)°. In the cry...

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Autores principales: Suhud, Khairi, Hasbullah, Siti Aishah, Ahmad, Musa, Heng, Lee Yook, Kassim, Mohammad B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730311/
https://www.ncbi.nlm.nih.gov/pubmed/29250374
http://dx.doi.org/10.1107/S2056989017013317
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author Suhud, Khairi
Hasbullah, Siti Aishah
Ahmad, Musa
Heng, Lee Yook
Kassim, Mohammad B.
author_facet Suhud, Khairi
Hasbullah, Siti Aishah
Ahmad, Musa
Heng, Lee Yook
Kassim, Mohammad B.
author_sort Suhud, Khairi
collection PubMed
description In the title compound, C(14)H(18)N(2)O(2)S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth­oxy­benzoyl ring, with a dihedral angle of 63.0 (3)°. The central N—C(=S)—N(H)—C(=O) bridge is twisted with an N—C—N—C torsion angle of 74.8 (6)°. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C—H⋯π inter­actions, forming layers parallel to the ac plane. The layers are linked by offset π–π inter­actions [inter­centroid distance = 3.927 (3) Å], forming a supra­molecular three-dimensional structure.
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spelling pubmed-57303112017-12-15 Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide Suhud, Khairi Hasbullah, Siti Aishah Ahmad, Musa Heng, Lee Yook Kassim, Mohammad B. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(14)H(18)N(2)O(2)S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth­oxy­benzoyl ring, with a dihedral angle of 63.0 (3)°. The central N—C(=S)—N(H)—C(=O) bridge is twisted with an N—C—N—C torsion angle of 74.8 (6)°. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C—H⋯π inter­actions, forming layers parallel to the ac plane. The layers are linked by offset π–π inter­actions [inter­centroid distance = 3.927 (3) Å], forming a supra­molecular three-dimensional structure. International Union of Crystallography 2017-09-25 /pmc/articles/PMC5730311/ /pubmed/29250374 http://dx.doi.org/10.1107/S2056989017013317 Text en © Suhud et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Suhud, Khairi
Hasbullah, Siti Aishah
Ahmad, Musa
Heng, Lee Yook
Kassim, Mohammad B.
Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title_full Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title_fullStr Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title_full_unstemmed Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title_short Crystal structure of 4-meth­oxy-N-(piperidine-1-carbono­thio­yl)benzamide
title_sort crystal structure of 4-meth­oxy-n-(piperidine-1-carbono­thio­yl)benzamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730311/
https://www.ncbi.nlm.nih.gov/pubmed/29250374
http://dx.doi.org/10.1107/S2056989017013317
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