Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate

Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C(8)H(13)N)(C(17)H(14)P)]Cl·H(2)O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­co...

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Detalles Bibliográficos
Autores principales: Zábranský, Martin, Štěpnička, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730313/
https://www.ncbi.nlm.nih.gov/pubmed/29250376
http://dx.doi.org/10.1107/S2056989017013408
Descripción
Sumario:Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C(8)H(13)N)(C(17)H(14)P)]Cl·H(2)O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­connected into chains by C—H⋯O inter­actions. The disubstituted ferrocene core in the {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°.

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