Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate

Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C(8)H(13)N)(C(17)H(14)P)]Cl·H(2)O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­co...

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Detalles Bibliográficos
Autores principales: Zábranský, Martin, Štěpnička, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730313/
https://www.ncbi.nlm.nih.gov/pubmed/29250376
http://dx.doi.org/10.1107/S2056989017013408
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author Zábranský, Martin
Štěpnička, Petr
author_facet Zábranský, Martin
Štěpnička, Petr
author_sort Zábranský, Martin
collection PubMed
description Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C(8)H(13)N)(C(17)H(14)P)]Cl·H(2)O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­connected into chains by C—H⋯O inter­actions. The disubstituted ferrocene core in the {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°.
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spelling pubmed-57303132017-12-15 Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate Zábranský, Martin Štěpnička, Petr Acta Crystallogr E Crystallogr Commun Research Communications Individual ions and the solvating water mol­ecule constituting the structure of the title compound, [Fe(C(8)H(13)N)(C(17)H(14)P)]Cl·H(2)O, assemble into dimeric units located around crystallographic inversion centers via N—H⋯Cl and O—H⋯Cl hydrogen bonds. These discrete fragments are further inter­connected into chains by C—H⋯O inter­actions. The disubstituted ferrocene core in the {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°. International Union of Crystallography 2017-09-25 /pmc/articles/PMC5730313/ /pubmed/29250376 http://dx.doi.org/10.1107/S2056989017013408 Text en © Zábranský and Štěpnička 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Zábranský, Martin
Štěpnička, Petr
Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title_full Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title_fullStr Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title_full_unstemmed Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title_short Crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
title_sort crystal structure of {[1′-(di­phenyl­phosphino)ferrocen­yl]meth­yl}di­methyl­ammonium chloride monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5730313/
https://www.ncbi.nlm.nih.gov/pubmed/29250376
http://dx.doi.org/10.1107/S2056989017013408
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