Cargando…

From a Decomposition Product to an Efficient and Versatile Catalyst: The [Ru(η(5)-indenyl)(PPh(3))(2)Cl] Story

[Image: see text] One of the most important challenges in catalyst design is the synthesis of stable promoters without compromising their activity. For this reason, it is important to understand the factors leading to decomposition of such catalysts, especially if side-products negatively affect the...

Descripción completa

Detalles Bibliográficos
Autores principales:	Manzini, Simone, Fernández-Salas, José A., Nolan, Steven P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5737444/ https://www.ncbi.nlm.nih.gov/pubmed/25264626 http://dx.doi.org/10.1021/ar500225j

Ejemplares similares

Bis(η(2)-ethylene)(η(5)-indenyl)iridium(I)
por: Merola, Joseph S.
Publicado: (2013)

Comparison of the catalytic activity for the Suzuki–Miyaura reaction of (η(5)-Cp)Pd(IPr)Cl with (η(3)-cinnamyl)Pd(IPr)(Cl) and (η(3)-1-t-Bu-indenyl)Pd(IPr)(Cl)
por: Melvin, Patrick R, et al.
Publicado: (2015)

Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II)
por: Oudenhoven, Tracey A., et al.
Publicado: (2010)

Crystal structures of di-μ-bromido-bis{dibromido[η(5)-2-(dimethylamino)indenyl]zirconium(IV)} and dibromidobis[η(5)-2-(dimethylamino)indenyl]zirconium(IV)
por: Medvedev, Michael G., et al.
Publicado: (2016)

Structure and Reactivity of [Ru–Al] and [Ru–Sn] Heterobimetallic PPh(3)-Based Complexes
por: Isaac, Connie J., et al.
Publicado: (2022)

RuO(2) Nanostructure as an Efficient and Versatile Catalyst for H(2) Photosynthesis
por: Bianco, Alberto, et al.
Publicado: (2023)

Multi‐Pathway Consequent Chemoselectivities of CpRuCl(PPh(3))(2)/MeI‐Catalysed Norbornadiene Alkyne Cycloadditions
por: Mu, Wei‐Hua, et al.
Publicado: (2016)

A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
por: Al-Majid, Abdullah M., et al.
Publicado: (2016)

Computational evaluation of the η6-arene during the ATH of imines on Noyori’s RuII catalyst
por: Kacer, Petr, et al.
Publicado: (2014)

Indenyl-thiazole and indenyl-formazan derivatives: Synthesis, anticancer screening studies, molecular-docking, and pharmacokinetic/ molin-spiration properties
por: Alfaifi, Ghaidaa H., et al.
Publicado: (2023)

[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]chlorido(η(5)-indenyl)ruthenium(II)
por: Sung, Hui-Ling, et al.
Publicado: (2011)

Azido[1,2-bis(diphenylphosphanyl)ethane-κ(2) P,P′](η(5)-indenyl)ruthenium(II)
por: Sung, Hui-Ling, et al.
Publicado: (2010)

Asymmetric transfer hydrogenation of imines and ketones using chiral Ru(II)Cl(η(6)-p-cymene)[(S,S)-N-TsDPEN] catalyst: a computational study
por: Kačer, Petr, et al.
Publicado: (2012)

Multiple light-induced NO linkage isomers in the dinitrosyl complex [RuCl(NO)(2)(PPh(3))(2)]BF(4) unravelled by photocrystallographic and IR analysis
por: Casaretto, Nicolas, et al.
Publicado: (2015)

Ru(0)·Ru(n+)/Al(2)O(3) as a Versatile Catalyst in the Isomerization of Allyl Alcohol
por: Enciso, Julián, et al.
Publicado: (2021)

Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au(11)(PPh(3))(7)Cl(3) and [Au(11)(PPh(3))(8)Cl(2)]Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione
por: McKenzie, Lallie C., et al.
Publicado: (2014)

Poly(alkylidenimine) Dendrimers Functionalized with the Organometallic Moiety [Ru(η(5)-C(5)H(5))(PPh(3))(2)](+) as Promising Drugs Against Cisplatin-Resistant Cancer Cells and Human Mesenchymal Stem Cells
por: Gouveia, Marisol, et al.
Publicado: (2018)

Reactivity of a Dinuclear Pd(I) Complex [Pd(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] with PPh(3): Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)(2)/nPPh(3) Catalyst System
por: Scott, Neil W. J., et al.
Publicado: (2021)

Efficient and Recyclable RuCl(3) ⋅ 3H(2)O Catalyst Modified with Ionic Diphosphine for the Alkoxycarbonylation of Aryl Halides
por: Zhou, Qing, et al.
Publicado: (2019)

Material Discovery and High Throughput Exploration of Ru Based Catalysts for Low Temperature Ammonia Decomposition
por: McCullough, Katherine, et al.
Publicado: (2020)

Neutral chiral cyclopentadienyl Ru(ii)Cl catalysts enable enantioselective [2+2]-cycloadditions
por: Kossler, D., et al.
Publicado: (2017)

Opportunities Offered by Chiral η(6)-Arene/N-Arylsulfonyl-diamine-Ru(II) Catalysts in the Asymmetric Transfer Hydrogenation of Ketones and Imines
por: Václavík, Jiří, et al.
Publicado: (2011)

The Significant Influence of a Second Metal on the Antiproliferative Properties of the Complex [Ru(η(6)−C(10)H(14))(Cl(2))(dmoPTA)]
por: Kordestani, Nazanin, et al.
Publicado: (2021)

Efficient NH(3)-based process to remove chlorine from electron beam deposited ruthenium produced from (η(3)-C(3)H(5))Ru(CO)(3)Cl
por: Rohdenburg, Markus, et al.
Publicado: (2020)

Postpartum haemorrhage (PPH) rates in randomized trials of PPH prophylactic interventions and the effect of underlying participant PPH risk: a meta-analysis
por: Hawker, Lydia, et al.
Publicado: (2020)

InCl(3): A Versatile Catalyst for Synthesizing a Broad Spectrum of Heterocycles
por: Mahato, Sanjit K., et al.
Publicado: (2020)

N(2)O decomposition properties of Ru catalysts supported on various oxide materials and SnO(2)
por: Hinokuma, Satoshi, et al.
Publicado: (2020)

Cytotoxic Assessment of 3,3-Dichloro-β-Lactams Prepared through Microwave-Assisted Benzylic C-H Activation from Benzyl-Tethered Trichloroacetamides Catalyzed by RuCl(2)(PPh(3))(3)
por: Diaba, Faïza, et al.
Publicado: (2022)

Di-μ-nitrosyl-bis[(η(5)-pentamethylcyclopentadienyl)ruthenium(0)](Ru—Ru). Corrigendum
por: Pearsal, Matthew, et al.
Publicado: (2010)

Synthesis and Anticancer Activity of [RuCl(2)(η(6)-arene)(aroylthiourea)] Complexes—High Activity against the Human Neuroblastoma (IMR-32) Cancer Cell Line
por: Swaminathan, Srividya, et al.
Publicado: (2019)

Combination of ruthenium(II)-arene complex [Ru(η(6)-p-cymene)Cl(2)(pta)] (RAPTA-C) and the epidermal growth factor receptor inhibitor erlotinib results in efficient angiostatic and antitumor activity
por: Berndsen, Robert H., et al.
Publicado: (2017)

Pt(PPh(3))(4) and Pt(PPh(3))(4)@IL catalyzed hydroboration of ketones
por: Krupa, Barbara, et al.
Publicado: (2023)

Metallic Barium: A Versatile and Efficient Hydrogenation Catalyst
por: Stegner, Philipp, et al.
Publicado: (2020)

Catalytic decomposition of hydroxylamine nitrate and hydrazine nitrate using Ru/ZSM-5 catalyst under mild reaction conditions
por: Zhang, Zhipeng, et al.
Publicado: (2022)

Ru-Doped Wells–Dawson Polyoxometalate as Efficient Catalyst for Glycerol Hydrogenolysis to Propanediols
por: Modvig, Amalie, et al.
Publicado: (2019)

Zinc‐Promoted ZnMe/ZnPh Exchange in Eight‐Coordinate [Ru(PPh(3))(2)(ZnMe)(4)H(2)]
por: Sotorrios, Lia, et al.
Publicado: (2022)

Nanostructured RuO(2)–Co(3)O(4)@RuCo-EO with low Ru loading as a high-efficiency electrochemical oxygen evolution catalyst
por: Tan, Lingjun, et al.
Publicado: (2021)

Kinetic and mechanistic analysis of NH(3) decomposition on Ru(0001), Ru(111) and Ir(111) surfaces
por: Lu, Xiuyuan, et al.
Publicado: (2021)

Chemistry of a novel zerovalent ruthenium π-acidic alkene complex, Ru (η(6)-1,3,5-cyclooctatriene)(η(2)-dimethyl fumarate)(2)
por: Mitsudo, Take-aki, et al.
Publicado: (2007)

Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh(3))(Br)](2)(μ,η(2)-C(4)H(3)N(2))(2), [Pd(Br)](2)(μ,η(2)-Hdppa)(2), and [{Pd(PPh(3))(CH(3)CN)}(2)(μ,η(2)-C(4)H(3)N(2))(2)][BF(4)](2)
por: Wang, Hsiao-Fen, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_lrcutth25r6tqcilnuv3svlrdt