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Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
In organic molecules, the reactivity at the carbon atom next to the functional group is dramatically different from that at other carbon atoms. Herein, we report that a versatile copper-catalyzed method enables successive dehydrogenation or dehydrogenation of ketones, aldehydes, alcohols, α,β-unsatu...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5741636/ https://www.ncbi.nlm.nih.gov/pubmed/29273723 http://dx.doi.org/10.1038/s41467-017-02381-8 |