Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation

The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system.

Detalles Bibliográficos
Autores principales: Wang, Qing-yao, Fang, Jia-qi, Deng, Lu-lu, Hao, Xiao-jiang, Mu, Shu-zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2017
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5745213/
https://www.ncbi.nlm.nih.gov/pubmed/29282557
http://dx.doi.org/10.1186/s13065-017-0368-z
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author Wang, Qing-yao
Fang, Jia-qi
Deng, Lu-lu
Hao, Xiao-jiang
Mu, Shu-zhen
author_facet Wang, Qing-yao
Fang, Jia-qi
Deng, Lu-lu
Hao, Xiao-jiang
Mu, Shu-zhen
author_sort Wang, Qing-yao
collection PubMed
description The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system.
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spelling pubmed-57452132018-01-19 Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation Wang, Qing-yao Fang, Jia-qi Deng, Lu-lu Hao, Xiao-jiang Mu, Shu-zhen Chem Cent J Research Article The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system. Springer International Publishing 2017-12-27 /pmc/articles/PMC5745213/ /pubmed/29282557 http://dx.doi.org/10.1186/s13065-017-0368-z Text en © The Author(s) 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated.
spellingShingle Research Article
Wang, Qing-yao
Fang, Jia-qi
Deng, Lu-lu
Hao, Xiao-jiang
Mu, Shu-zhen
Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title_full Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title_fullStr Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title_full_unstemmed Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title_short Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
title_sort regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5745213/
https://www.ncbi.nlm.nih.gov/pubmed/29282557
http://dx.doi.org/10.1186/s13065-017-0368-z
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