Cargando…

Chemoselective Aliphatic C–H Bond Oxidation Enabled by Polarity Reversal

[Image: see text] Methods for selective oxidation of aliphatic C–H bonds are called on to revolutionize organic synthesis by providing novel and more efficient paths. Realization of this goal requires the discovery of mechanisms that can alter in a predictable manner the innate reactivity of these b...

Descripción completa

Detalles Bibliográficos
Autores principales:	Dantignana, Valeria, Milan, Michela, Cussó, Olaf, Company, Anna, Bietti, Massimo, Costas, Miquel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5746866/ https://www.ncbi.nlm.nih.gov/pubmed/29296677 http://dx.doi.org/10.1021/acscentsci.7b00532

Ejemplares similares

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
por: Milan, Michela, et al.
Publicado: (2017)

Highly Selective C(sp(3))–H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhancement
por: Sisti, Sergio, et al.
Publicado: (2023)

C–H Bonds as Functional Groups: Simultaneous Generation of Multiple Stereocenters by Enantioselective Hydroxylation at Unactivated Tertiary C–H Bonds
por: Palone, Andrea, et al.
Publicado: (2023)

Chemoselective formal β-functionalization of substituted aliphatic amides enabled by a facile stereoselective oxidation event
por: Bauer, Adriano, et al.
Publicado: (2019)

Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp(3))–H Functionalization via Radical and Cationic Intermediates
por: Galeotti, Marco, et al.
Publicado: (2022)

Direct Arylation of Strong Aliphatic C–H Bonds
por: Perry, Ian B., et al.
Publicado: (2018)

Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ-C–H Bonds
por: Call, Arnau, et al.
Publicado: (2023)

Chemoselective carbene insertion into the N−H bonds of NH(3)·H(2)O
por: Liu, Zhaohong, et al.
Publicado: (2022)

Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
por: Short, Melanie A., et al.
Publicado: (2019)

Carboxylic Acid Directed γ-Lactonization of Unactivated Primary C–H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification
por: Call, Arnau, et al.
Publicado: (2022)

Factors Governing Reactivity and Selectivity in Hydrogen Atom Transfer from C(sp(3))–H Bonds of Nitrogen-Containing Heterocycles to the Cumyloxyl Radical
por: Galeotti, Marco, et al.
Publicado: (2022)

Enzymatic Hydroxylation of Aliphatic C-H Bonds by a Mn/Fe Cofactor
por: Powell, Magan M., et al.
Publicado: (2023)

Enzymatic Hydroxylation of Aliphatic C–H Bonds by a Mn/Fe Cofactor
por: Powell, Magan M., et al.
Publicado: (2023)

Diazo Groups Endure Metabolism and Enable Chemoselectivity in Cellulo
por: Andersen, Kristen A., et al.
Publicado: (2015)

Site-selective functionalization of remote aliphatic C–H bonds via C–H metallation
por: Zhang, Qi, et al.
Publicado: (2020)

Chemoselective Activation of sp(3) vs sp(2) C–H Bonds with Pd(II)
por: Curto, John M., et al.
Publicado: (2014)

Transition metal-free intramolecular regioselective couplings of aliphatic and aromatic C-H bonds
por: Tian, Hua, et al.
Publicado: (2016)

Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C–H Bonds Elaboration
por: Capaldo, Luca, et al.
Publicado: (2021)

SuFEx-enabled, chemoselective synthesis of triflates, triflamides and triflimidates
por: Li, Bing-Yu, et al.
Publicado: (2022)

Radical and Cationic Pathways in C(sp(3))–H Bond Oxygenation by Dioxiranes of Bicyclic and Spirocyclic Hydrocarbons Bearing Cyclopropane Moieties
por: Galeotti, Marco, et al.
Publicado: (2023)

Chemoselective Installation of Amine Bonds on Proteins through Aza-Michael Ligation
por: Freedy, Allyson M., et al.
Publicado: (2017)

Correction: SuFEx-enabled, chemoselective synthesis of triflates, triflamides and triflimidates
por: Li, Bing-Yu, et al.
Publicado: (2022)

Practical and Selective sp(3) C−H Bond Chlorination via Aminium Radicals
por: McMillan, Alastair J., et al.
Publicado: (2021)

Visible Light‐Enabled sp(3)‐C−H Functionalization with Chloro‐ and Bromoalkynes: Chemoselective Route to Vinylchlorides or Alkynes
por: Adak, Tapas, et al.
Publicado: (2020)

Bio-Based Thermo-Reversible Aliphatic Polycarbonate Network
por: Durand, Pierre-Luc, et al.
Publicado: (2019)

A Supported Bismuth Halide Perovskite Photocatalyst for Selective Aliphatic and Aromatic C–H Bond Activation
por: Dai, Yitao, et al.
Publicado: (2020)

The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes
por: Somekh, Miriam, et al.
Publicado: (2020)

Chemoselectivity in the Oxidation of Cycloalkenes with a Non-Heme Iron(IV)-Oxo-Chloride Complex: Epoxidation vs. Hydroxylation Selectivity
por: Terencio, Thibault, et al.
Publicado: (2019)

Pd-Catalyzed Organometallic-Free Homologation of Arylboronic Acids Enabled by Chemoselective Transmetalation
por: Bastick, Kane A. C., et al.
Publicado: (2023)

Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs
por: Xu, Pengfei, et al.
Publicado: (2018)

A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides
por: Cussó, Olaf, et al.
Publicado: (2017)

Diverse secondary C(sp(3))–H bond functionalization via site-selective trifluoroacetoxylation of aliphatic amines
por: Tang, Yongzhen, et al.
Publicado: (2018)

A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds
por: Wang, Yaxin, et al.
Publicado: (2016)

Reversible stapling of unprotected peptides via chemoselective methionine bis-alkylation/dealkylation
por: Shi, Xiaodong, et al.
Publicado: (2018)

Effective Tetradentate Compound Complexes against Leishmania spp. that Act on Critical Enzymatic Pathways of These Parasites
por: Urbanová, Kristína, et al.
Publicado: (2018)

Chemoselective Acylation of Nucleosides
por: Tang, Yu, et al.
Publicado: (2022)

Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer
por: Molloy, John J., et al.
Publicado: (2017)

Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C–C Bonds
por: Barata-Vallejo, Sebastián, et al.
Publicado: (2019)

Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines
por: Adeniyi, Emmanuel, et al.
Publicado: (2022)

Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds
por: Gao, Yiman, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_l7e6tkc4qd9p06iq8k53g6tnqf