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Synthesis of Formate Esters and Formamides Using an Au/TiO(2)-Catalyzed Aerobic Oxidative Coupling of Paraformaldehyde

A simple method for the synthesis of formate esters and formamides is presented based on the Au/TiO(2)-catalyzed aerobic oxidative coupling between alcohols or amines and formaldehyde. The suitable form of formaldehyde is paraformaldehyde, as cyclic trimeric 1,3,5-trioxane is inactive. The reaction...

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Detalles Bibliográficos
Autores principales: Metaxas, Ioannis, Vasilikogiannaki, Eleni, Stratakis, Manolis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5746930/
https://www.ncbi.nlm.nih.gov/pubmed/29231853
http://dx.doi.org/10.3390/nano7120440

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