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Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investi...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5746948/ https://www.ncbi.nlm.nih.gov/pubmed/29257075 http://dx.doi.org/10.3390/nano7120459 |
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author | Hu, Jun Zhu, Chaojie Xia, Feifei Fang, Zhongxue Yang, Fengli Weng, Jushi Yao, Pengfei Zheng, Chunzhi Dong, Hai Fu, Wenqian |
author_facet | Hu, Jun Zhu, Chaojie Xia, Feifei Fang, Zhongxue Yang, Fengli Weng, Jushi Yao, Pengfei Zheng, Chunzhi Dong, Hai Fu, Wenqian |
author_sort | Hu, Jun |
collection | PubMed |
description | Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investigate their catalytic performances in the hydroxysulfurization of styrenes with diaryl disulfides. The effect of pore size and acidities of the supports, as well as the Cu species electronic properties of the catalysts on reaction activity were investigated. The results show that Cu(+) and Cu(2+) binded on HZSM-5-M show the highest activity and product selectivity for the desired β-hydroxysulfides compounds. |
format | Online Article Text |
id | pubmed-5746948 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-57469482018-01-03 Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides Hu, Jun Zhu, Chaojie Xia, Feifei Fang, Zhongxue Yang, Fengli Weng, Jushi Yao, Pengfei Zheng, Chunzhi Dong, Hai Fu, Wenqian Nanomaterials (Basel) Article Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investigate their catalytic performances in the hydroxysulfurization of styrenes with diaryl disulfides. The effect of pore size and acidities of the supports, as well as the Cu species electronic properties of the catalysts on reaction activity were investigated. The results show that Cu(+) and Cu(2+) binded on HZSM-5-M show the highest activity and product selectivity for the desired β-hydroxysulfides compounds. MDPI 2017-12-19 /pmc/articles/PMC5746948/ /pubmed/29257075 http://dx.doi.org/10.3390/nano7120459 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Hu, Jun Zhu, Chaojie Xia, Feifei Fang, Zhongxue Yang, Fengli Weng, Jushi Yao, Pengfei Zheng, Chunzhi Dong, Hai Fu, Wenqian Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title | Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title_full | Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title_fullStr | Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title_full_unstemmed | Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title_short | Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides |
title_sort | acidic mesoporous zeolite zsm-5 supported cu catalyst with good catalytic performance in the hydroxysulfurization of styrenes with disulfides |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5746948/ https://www.ncbi.nlm.nih.gov/pubmed/29257075 http://dx.doi.org/10.3390/nano7120459 |
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