CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na

Sodium trifluoromethanesulfinate, CF(3)SO(2)Na, and trifluoromethanesulfonyl chloride, CF(3)SO(2)Cl, are two popular reagents that are widely used for the direct trifluoromethylation of a large range of substrates. Further, these two reagents are employed for the direct trifluoromethylsulfenylation...

Descripción completa

Detalles Bibliográficos
Autores principales: Guyon, Hélène, Chachignon, Hélène, Cahard, Dominique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5753172/
https://www.ncbi.nlm.nih.gov/pubmed/30018665
http://dx.doi.org/10.3762/bjoc.13.272
_version_ 1783290221622722560
author Guyon, Hélène
Chachignon, Hélène
Cahard, Dominique
author_facet Guyon, Hélène
Chachignon, Hélène
Cahard, Dominique
author_sort Guyon, Hélène
collection PubMed
description Sodium trifluoromethanesulfinate, CF(3)SO(2)Na, and trifluoromethanesulfonyl chloride, CF(3)SO(2)Cl, are two popular reagents that are widely used for the direct trifluoromethylation of a large range of substrates. Further, these two reagents are employed for the direct trifluoromethylsulfenylation and trifluoromethylsulfinylation, the introduction of the SCF(3) and the S(O)CF(3) group, respectively. In addition to the aforementioned reactions, the versatility of these two reagents is presented in other reactions such as sulfonylation and chlorination. This first part is dedicated to sodium trifluoromethanesulfinate.
format Online
Article
Text
id pubmed-5753172
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-57531722018-07-17 CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na Guyon, Hélène Chachignon, Hélène Cahard, Dominique Beilstein J Org Chem Full Research Paper Sodium trifluoromethanesulfinate, CF(3)SO(2)Na, and trifluoromethanesulfonyl chloride, CF(3)SO(2)Cl, are two popular reagents that are widely used for the direct trifluoromethylation of a large range of substrates. Further, these two reagents are employed for the direct trifluoromethylsulfenylation and trifluoromethylsulfinylation, the introduction of the SCF(3) and the S(O)CF(3) group, respectively. In addition to the aforementioned reactions, the versatility of these two reagents is presented in other reactions such as sulfonylation and chlorination. This first part is dedicated to sodium trifluoromethanesulfinate. Beilstein-Institut 2017-12-19 /pmc/articles/PMC5753172/ /pubmed/30018665 http://dx.doi.org/10.3762/bjoc.13.272 Text en Copyright © 2017, Guyon et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Guyon, Hélène
Chachignon, Hélène
Cahard, Dominique
CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title_full CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title_fullStr CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title_full_unstemmed CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title_short CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
title_sort cf(3)so(2)x (x = na, cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. part 1: use of cf(3)so(2)na
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5753172/
https://www.ncbi.nlm.nih.gov/pubmed/30018665
http://dx.doi.org/10.3762/bjoc.13.272
work_keys_str_mv AT guyonhelene cf3so2xxnaclasreagentsfortrifluoromethylationtrifluoromethylsulfenylsulfinylandsulfonylationpart1useofcf3so2na
AT chachignonhelene cf3so2xxnaclasreagentsfortrifluoromethylationtrifluoromethylsulfenylsulfinylandsulfonylationpart1useofcf3so2na
AT caharddominique cf3so2xxnaclasreagentsfortrifluoromethylationtrifluoromethylsulfenylsulfinylandsulfonylationpart1useofcf3so2na

Ejemplares similares