Cargando…
CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF(3)SO(2)Na
Sodium trifluoromethanesulfinate, CF(3)SO(2)Na, and trifluoromethanesulfonyl chloride, CF(3)SO(2)Cl, are two popular reagents that are widely used for the direct trifluoromethylation of a large range of substrates. Further, these two reagents are employed for the direct trifluoromethylsulfenylation...
Autores principales: | Guyon, Hélène, Chachignon, Hélène, Cahard, Dominique |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5753172/ https://www.ncbi.nlm.nih.gov/pubmed/30018665 http://dx.doi.org/10.3762/bjoc.13.272 |
Ejemplares similares
-
CF(3)SO(2)X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF(3)SO(2)Cl
por: Chachignon, Hélène, et al.
Publicado: (2017) -
Metal-free oxidative trifluoromethylation of indoles with CF(3)SO(2)Na on the C2 position
por: Xie, Jiao-Jiao, et al.
Publicado: (2019) -
Trifluoromethyl
Thianthrenium Triflate: A Readily
Available Trifluoromethylating Reagent with Formal CF(3)(+), CF(3)(•), and CF(3)(–) Reactivity
por: Jia, Hao, et al.
Publicado: (2021) -
Theoretical insight into OH- and Cl-initiated oxidation of CF(3)OCH(CF(3))(2) and CF(3)OCF(2)CF(2)H & fate of CF(3)OC(X•)(CF(3))(2) and CF(3)OCF(2)CF(2)X• radicals (X=O, O(2))
por: Bai, Feng-Yang, et al.
Publicado: (2017) -
Photoinduced Trifluoromethylation with CF(3)Br as a Trifluoromethyl
Source: Synthesis of α-CF(3)-Substituted
Ketones
por: Ma, Ransong, et al.
Publicado: (2022)