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Close contacts involving germanium and tin in crystal structures: experimental evidence of tetrel bonds
Modeling indicates the presence of a region of low electronic density (a “σ-hole”) on group 14 elements, and this offers an explanation for the ability of these elements to act as electrophilic sites and to form attractive interactions with nucleophiles. While many papers have described theoretical...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Berlin Heidelberg
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5758658/ https://www.ncbi.nlm.nih.gov/pubmed/29313131 http://dx.doi.org/10.1007/s00894-017-3573-8 |