Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates

Many-body effects produce deviations from the predictions of conventional band theory in quantum materials, leading to strongly correlated phases with insulating or bad metallic behavior. One example is the rare-earth nickelates RNiO(3), which undergo metal-to-insulator transitions (MITs) whose origin is debated. Here, we combine total neutron scattering and broadband dielectric spectroscopy experiments to study and compare carrier dynamics and local crystal structure in LaNiO(3) and NdNiO(3). We find that the local crystal structure of both materials is distorted in the metallic phase, with slow, thermally activated carrier dynamics at high temperature. We further observe a sharp change in conductivity across the MIT in NdNiO(3), accompanied by slight differences in the carrier hopping time. These results suggest that changes in carrier concentration drive the MIT through a polaronic mechanism, where the (bi)polaron liquid freezes into the insulating phase across the MIT temperature.