Kinetics of the Strain-Promoted Oxidation-Controlled Cycloalkyne-1,2-quinone Cycloaddition: Experimental and Theoretical Studies

[Image: see text] Stimulated by its success in both bioconjugation and surface modification, we studied the strain-promoted oxidation-controlled cycloalkyne–1,2-quinone cycloaddition (SPOCQ) in three ways. First, the second-order rate constants and activation parameters (ΔH(⧧)) were determined of va...

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Detalles Bibliográficos
Autores principales: Escorihuela, Jorge, Das, Anita, Looijen, Wilhelmus J. E., van Delft, Floris L., Aquino, Adelia J. A., Lischka, Hans, Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5759032/
https://www.ncbi.nlm.nih.gov/pubmed/29260879
http://dx.doi.org/10.1021/acs.joc.7b02614

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