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A Novel Open-Framework Cu-Ge-Based Chalcogenide Anode Material for Sodium-Ion Battery

Open-framework chalcogenides are potential electrode materials for sodium-ion batteries (SIBs) due to their architectures with fast-ion conductivity. Herein, we report on the successful synthesis of open-framework Cu-Ge-based chalcogenides [Cu(8)Ge(6)Se(19)](C(5)H(12)N)(6) (CGSe) and the research of...

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Detalles Bibliográficos
Autores principales: Sun, Quan, Fu, Lin, Shang, Chaoqun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5763134/
https://www.ncbi.nlm.nih.gov/pubmed/29445427
http://dx.doi.org/10.1155/2017/3876525
Descripción
Sumario:Open-framework chalcogenides are potential electrode materials for sodium-ion batteries (SIBs) due to their architectures with fast-ion conductivity. Herein, we report on the successful synthesis of open-framework Cu-Ge-based chalcogenides [Cu(8)Ge(6)Se(19)](C(5)H(12)N)(6) (CGSe) and the research of their energy storage application as SIB anodes for the first time. As a result, the CGSe anode exhibited good electrochemical performances such as high reversible capacity (463.3 mAh g(−1)), excellent rate performance, and considerable cycling stability. Our exploration not only develops a promising electrode material for SIBs, but also extends the application of open-framework chalcogenides.