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Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization

Achieving selective C–H functionalization is a significant challenge that requires discrimination between many similar C–H bonds. Yet, reaction systems employing Rh(2)(DOSP)(4) and Rh(2)(BPCP)(4) were recently demonstrated to afford high levels of selectivity in the C–H insertion of carbenes into to...

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Detalles Bibliográficos
Autores principales:	Bess, Elizabeth N., Guptill, David M., Davies, Huw M. L., Sigman, Matthew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5763982/ https://www.ncbi.nlm.nih.gov/pubmed/29403640 http://dx.doi.org/10.1039/c5sc00357a

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