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Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex

One‐electron oxidation of the rhodium(I) azido complex [Rh(N(3))(PNP)] (5), bearing the neutral, pyridine‐based PNP ligand 2,6‐bis(di‐tert‐butylphosphinomethyl)pyridine, leads to instantaneous and selective formation of the mononuclear rhodium(I) dinitrogen complex [Rh(N(2))(PNP)](+) (9 (+)). Intere...

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Detalles Bibliográficos
Autores principales:	Rebreyend, Christophe, Gloaguen, Yann, Lutz, Martin, van der Vlugt, Jarl Ivar, Siewert, Inke, Schneider, Sven, de Bruin, Bas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765409/ https://www.ncbi.nlm.nih.gov/pubmed/28898478 http://dx.doi.org/10.1002/chem.201702938

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