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Sulfonylative and Azidosulfonylative Cyclizations by Visible‐Light‐Photosensitization of Sulfonyl Azides in THF

The generation of sulfonyl radicals from sulfonyl azides using visible light and a photoactive iridium complex in THF is described. This process was used to promote sulfonylative and azidosulfonylative cyclizations of enynes to give several classes of highly functionalized heterocycles. The use of T...

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Detalles Bibliográficos
Autores principales: Zhu, Shaoqun, Pathigoolla, Atchutarao, Lowe, Grace, Walsh, Darren A., Cooper, Mick, Lewis, William, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765429/
https://www.ncbi.nlm.nih.gov/pubmed/28945301
http://dx.doi.org/10.1002/chem.201704380

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