N‐Heterocyclic Carbene Self‐assembled Monolayers on Copper and Gold: Dramatic Effect of Wingtip Groups on Binding, Orientation and Assembly

Self‐assembled monolayers of N‐heterocyclic carbenes (NHCs) on copper are reported. The monolayer structure is highly dependent on the N,N‐substituents on the NHC. On both Cu(111) and Au(111), bulky isopropyl substituents force the NHC to bind perpendicular to the metal surface while methyl‐ or ethy...

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Detalles Bibliográficos
Autores principales: Larrea, Christian R., Baddeley, Christopher J., Narouz, Mina R., Mosey, Nicholas J., Horton, J. Hugh, Crudden, Cathleen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5765499/
https://www.ncbi.nlm.nih.gov/pubmed/28960768
http://dx.doi.org/10.1002/cphc.201701045

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