Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries

Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited...

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Autores principales: Shimizu, Takeshi, Yamamoto, Koji, Pandit, Palash, Yoshikawa, Hirofumi, Higashibayashi, Shuhei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5766615/
https://www.ncbi.nlm.nih.gov/pubmed/29330491
http://dx.doi.org/10.1038/s41598-017-19037-8
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author Shimizu, Takeshi
Yamamoto, Koji
Pandit, Palash
Yoshikawa, Hirofumi
Higashibayashi, Shuhei
author_facet Shimizu, Takeshi
Yamamoto, Koji
Pandit, Palash
Yoshikawa, Hirofumi
Higashibayashi, Shuhei
author_sort Shimizu, Takeshi
collection PubMed
description Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited clear plateaus in the high voltage range of 3.3–3.7 V. The capacities of the plateau regions were comparable to the calculated capacities corresponding to the one-electron redox of the molecules. The amount of the active compound 3b could be increased up to 30 wt% in the electrode composite, and fast charge/discharge performance was also observed.
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spelling pubmed-57666152018-01-25 Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries Shimizu, Takeshi Yamamoto, Koji Pandit, Palash Yoshikawa, Hirofumi Higashibayashi, Shuhei Sci Rep Article Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited clear plateaus in the high voltage range of 3.3–3.7 V. The capacities of the plateau regions were comparable to the calculated capacities corresponding to the one-electron redox of the molecules. The amount of the active compound 3b could be increased up to 30 wt% in the electrode composite, and fast charge/discharge performance was also observed. Nature Publishing Group UK 2018-01-12 /pmc/articles/PMC5766615/ /pubmed/29330491 http://dx.doi.org/10.1038/s41598-017-19037-8 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Shimizu, Takeshi
Yamamoto, Koji
Pandit, Palash
Yoshikawa, Hirofumi
Higashibayashi, Shuhei
Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_full Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_fullStr Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_full_unstemmed Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_short Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_sort application of hydrazine-embedded heterocyclic compounds to high voltage rechargeable lithium organic batteries
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5766615/
https://www.ncbi.nlm.nih.gov/pubmed/29330491
http://dx.doi.org/10.1038/s41598-017-19037-8
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