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Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates

The metalloradical activation of ortho‐benzallylaryl N‐tosyl hydrazones with [Co(TPP)] (TPP=tetraphenylporphyrin) as the catalyst enabled the controlled exploitation of the single‐electron reactivity of the redox non‐innocent carbene intermediate. This method offers a novel route to prepare eight‐me...

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Detalles Bibliográficos
Autores principales:	te Grotenhuis, Colet, van den Heuvel, Naudin, van der Vlugt, Jarl Ivar, de Bruin, Bas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767734/ https://www.ncbi.nlm.nih.gov/pubmed/29155465 http://dx.doi.org/10.1002/anie.201711028

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