Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides

Readily accessed cobalt pre‐catalysts with N‐heterocyclic carbene ligands catalyze the Suzuki cross‐coupling of aryl chlorides and bromides with alkyllithium‐activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co(0) during the react...

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Detalles Bibliográficos
Autores principales: Asghar, Soneela, Tailor, Sanita B., Elorriaga, David, Bedford, Robin B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767760/
https://www.ncbi.nlm.nih.gov/pubmed/29135071
http://dx.doi.org/10.1002/anie.201710053
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author Asghar, Soneela
Tailor, Sanita B.
Elorriaga, David
Bedford, Robin B.
author_facet Asghar, Soneela
Tailor, Sanita B.
Elorriaga, David
Bedford, Robin B.
author_sort Asghar, Soneela
collection PubMed
description Readily accessed cobalt pre‐catalysts with N‐heterocyclic carbene ligands catalyze the Suzuki cross‐coupling of aryl chlorides and bromides with alkyllithium‐activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co(0) during the reaction.
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spelling pubmed-57677602018-02-01 Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides Asghar, Soneela Tailor, Sanita B. Elorriaga, David Bedford, Robin B. Angew Chem Int Ed Engl Communications Readily accessed cobalt pre‐catalysts with N‐heterocyclic carbene ligands catalyze the Suzuki cross‐coupling of aryl chlorides and bromides with alkyllithium‐activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co(0) during the reaction. John Wiley and Sons Inc. 2017-11-28 2017-12-18 /pmc/articles/PMC5767760/ /pubmed/29135071 http://dx.doi.org/10.1002/anie.201710053 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Asghar, Soneela
Tailor, Sanita B.
Elorriaga, David
Bedford, Robin B.
Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title_full Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title_fullStr Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title_full_unstemmed Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title_short Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
title_sort cobalt‐catalyzed suzuki biaryl coupling of aryl halides
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767760/
https://www.ncbi.nlm.nih.gov/pubmed/29135071
http://dx.doi.org/10.1002/anie.201710053
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AT elorriagadavid cobaltcatalyzedsuzukibiarylcouplingofarylhalides
AT bedfordrobinb cobaltcatalyzedsuzukibiarylcouplingofarylhalides

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