The Palladium Acetate‐Catalyzed Microwave‐Assisted Hirao Reaction without an Added Phosphorus Ligand as a “Green” Protocol: A Quantum Chemical Study on the Mechanism

It was proved by our experiments that on microwave irradiation, the mono‐ or bidentate phosphorus ligands generally applied in the palladium(II)‐catalyzed P–C coupling reaction of aryl bromides and dialkyl phosphites or secondary phosphine oxides may be substituted by the excess of the >P(O)H rea...

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Detalles Bibliográficos
Autores principales: Keglevich, György, Henyecz, Réka, Mucsi, Zoltán, Kiss, Nóra Zs.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767766/
https://www.ncbi.nlm.nih.gov/pubmed/29399016
http://dx.doi.org/10.1002/adsc.201700895

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5767766/
https://www.ncbi.nlm.nih.gov/pubmed/29399016
http://dx.doi.org/10.1002/adsc.201700895

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