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Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768023/ https://www.ncbi.nlm.nih.gov/pubmed/29193535 http://dx.doi.org/10.1002/anie.201710467 |
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author | Cortizo‐Lacalle, Diego Mora‐Fuentes, Juan P. Strutyński, Karol Saeki, Akinori Melle‐Franco, Manuel Mateo‐Alonso, Aurelio |
author_facet | Cortizo‐Lacalle, Diego Mora‐Fuentes, Juan P. Strutyński, Karol Saeki, Akinori Melle‐Franco, Manuel Mateo‐Alonso, Aurelio |
author_sort | Cortizo‐Lacalle, Diego |
collection | PubMed |
description | The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications. An iterative approach is presented that assembles a small and carefully designed molecular building block into monodisperse N‐doped graphene nanoribbons with different lengths. To showcase this approach, the synthesis and characterisation of a series of nanoribbons constituted of 10, 20 and 30 conjugated linearly‐fused rings (2.9, 5.3, and 7.7 nm in length, respectively) is presented. |
format | Online Article Text |
id | pubmed-5768023 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-57680232018-02-01 Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length Cortizo‐Lacalle, Diego Mora‐Fuentes, Juan P. Strutyński, Karol Saeki, Akinori Melle‐Franco, Manuel Mateo‐Alonso, Aurelio Angew Chem Int Ed Engl Communications The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications. An iterative approach is presented that assembles a small and carefully designed molecular building block into monodisperse N‐doped graphene nanoribbons with different lengths. To showcase this approach, the synthesis and characterisation of a series of nanoribbons constituted of 10, 20 and 30 conjugated linearly‐fused rings (2.9, 5.3, and 7.7 nm in length, respectively) is presented. John Wiley and Sons Inc. 2017-12-18 2018-01-15 /pmc/articles/PMC5768023/ /pubmed/29193535 http://dx.doi.org/10.1002/anie.201710467 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
spellingShingle | Communications Cortizo‐Lacalle, Diego Mora‐Fuentes, Juan P. Strutyński, Karol Saeki, Akinori Melle‐Franco, Manuel Mateo‐Alonso, Aurelio Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title | Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title_full | Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title_fullStr | Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title_full_unstemmed | Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title_short | Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length |
title_sort | monodisperse n‐doped graphene nanoribbons reaching 7.7 nanometers in length |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768023/ https://www.ncbi.nlm.nih.gov/pubmed/29193535 http://dx.doi.org/10.1002/anie.201710467 |
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