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Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length

The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications...

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Detalles Bibliográficos
Autores principales: Cortizo‐Lacalle, Diego, Mora‐Fuentes, Juan P., Strutyński, Karol, Saeki, Akinori, Melle‐Franco, Manuel, Mateo‐Alonso, Aurelio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768023/
https://www.ncbi.nlm.nih.gov/pubmed/29193535
http://dx.doi.org/10.1002/anie.201710467
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author Cortizo‐Lacalle, Diego
Mora‐Fuentes, Juan P.
Strutyński, Karol
Saeki, Akinori
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
author_facet Cortizo‐Lacalle, Diego
Mora‐Fuentes, Juan P.
Strutyński, Karol
Saeki, Akinori
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
author_sort Cortizo‐Lacalle, Diego
collection PubMed
description The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications. An iterative approach is presented that assembles a small and carefully designed molecular building block into monodisperse N‐doped graphene nanoribbons with different lengths. To showcase this approach, the synthesis and characterisation of a series of nanoribbons constituted of 10, 20 and 30 conjugated linearly‐fused rings (2.9, 5.3, and 7.7 nm in length, respectively) is presented.
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spelling pubmed-57680232018-02-01 Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length Cortizo‐Lacalle, Diego Mora‐Fuentes, Juan P. Strutyński, Karol Saeki, Akinori Melle‐Franco, Manuel Mateo‐Alonso, Aurelio Angew Chem Int Ed Engl Communications The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications. An iterative approach is presented that assembles a small and carefully designed molecular building block into monodisperse N‐doped graphene nanoribbons with different lengths. To showcase this approach, the synthesis and characterisation of a series of nanoribbons constituted of 10, 20 and 30 conjugated linearly‐fused rings (2.9, 5.3, and 7.7 nm in length, respectively) is presented. John Wiley and Sons Inc. 2017-12-18 2018-01-15 /pmc/articles/PMC5768023/ /pubmed/29193535 http://dx.doi.org/10.1002/anie.201710467 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Cortizo‐Lacalle, Diego
Mora‐Fuentes, Juan P.
Strutyński, Karol
Saeki, Akinori
Melle‐Franco, Manuel
Mateo‐Alonso, Aurelio
Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title_full Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title_fullStr Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title_full_unstemmed Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title_short Monodisperse N‐Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
title_sort monodisperse n‐doped graphene nanoribbons reaching 7.7 nanometers in length
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5768023/
https://www.ncbi.nlm.nih.gov/pubmed/29193535
http://dx.doi.org/10.1002/anie.201710467
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