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Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide

In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the imino and meth­oxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains propa...

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Detalles Bibliográficos
Autores principales: Yaman, Mavişe, Almarhoon, Zainab M., Çakmak, Şükriye, Kütük, Halil, Meral, Güngör, Dege, Necmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/
https://www.ncbi.nlm.nih.gov/pubmed/29416888
http://dx.doi.org/10.1107/S2056989017017741
Descripción
Sumario:In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the imino and meth­oxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the inter­molecular inter­actions present in the crystal.