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Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide
In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propa...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/ https://www.ncbi.nlm.nih.gov/pubmed/29416888 http://dx.doi.org/10.1107/S2056989017017741 |
Sumario: | In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the intermolecular interactions present in the crystal. |
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