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Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide
In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propa...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/ https://www.ncbi.nlm.nih.gov/pubmed/29416888 http://dx.doi.org/10.1107/S2056989017017741 |
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author | Yaman, Mavişe Almarhoon, Zainab M. Çakmak, Şükriye Kütük, Halil Meral, Güngör Dege, Necmi |
author_facet | Yaman, Mavişe Almarhoon, Zainab M. Çakmak, Şükriye Kütük, Halil Meral, Güngör Dege, Necmi |
author_sort | Yaman, Mavişe |
collection | PubMed |
description | In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the intermolecular interactions present in the crystal. |
format | Online Article Text |
id | pubmed-5778482 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-57784822018-02-07 Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide Yaman, Mavişe Almarhoon, Zainab M. Çakmak, Şükriye Kütük, Halil Meral, Güngör Dege, Necmi Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the intermolecular interactions present in the crystal. International Union of Crystallography 2018-01-01 /pmc/articles/PMC5778482/ /pubmed/29416888 http://dx.doi.org/10.1107/S2056989017017741 Text en © Yaman et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Yaman, Mavişe Almarhoon, Zainab M. Çakmak, Şükriye Kütük, Halil Meral, Güngör Dege, Necmi Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title | Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title_full | Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title_fullStr | Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title_full_unstemmed | Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title_short | Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide |
title_sort | crystal structure of 2,3-dimethoxy-n-(4-nitrophenyl)benzamide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/ https://www.ncbi.nlm.nih.gov/pubmed/29416888 http://dx.doi.org/10.1107/S2056989017017741 |
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