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Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide

In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the imino and meth­oxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains propa...

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Autores principales: Yaman, Mavişe, Almarhoon, Zainab M., Çakmak, Şükriye, Kütük, Halil, Meral, Güngör, Dege, Necmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/
https://www.ncbi.nlm.nih.gov/pubmed/29416888
http://dx.doi.org/10.1107/S2056989017017741
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author Yaman, Mavişe
Almarhoon, Zainab M.
Çakmak, Şükriye
Kütük, Halil
Meral, Güngör
Dege, Necmi
author_facet Yaman, Mavişe
Almarhoon, Zainab M.
Çakmak, Şükriye
Kütük, Halil
Meral, Güngör
Dege, Necmi
author_sort Yaman, Mavişe
collection PubMed
description In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the imino and meth­oxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the inter­molecular inter­actions present in the crystal.
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spelling pubmed-57784822018-02-07 Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide Yaman, Mavişe Almarhoon, Zainab M. Çakmak, Şükriye Kütük, Halil Meral, Güngör Dege, Necmi Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(14)N(2)O(5), the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the imino and meth­oxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the inter­molecular inter­actions present in the crystal. International Union of Crystallography 2018-01-01 /pmc/articles/PMC5778482/ /pubmed/29416888 http://dx.doi.org/10.1107/S2056989017017741 Text en © Yaman et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Yaman, Mavişe
Almarhoon, Zainab M.
Çakmak, Şükriye
Kütük, Halil
Meral, Güngör
Dege, Necmi
Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title_full Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title_fullStr Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title_full_unstemmed Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title_short Crystal structure of 2,3-dimeth­oxy-N-(4-nitro­phen­yl)benzamide
title_sort crystal structure of 2,3-dimeth­oxy-n-(4-nitro­phen­yl)benzamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5778482/
https://www.ncbi.nlm.nih.gov/pubmed/29416888
http://dx.doi.org/10.1107/S2056989017017741
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