Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides

The photocatalyzed synthesis of sulfoxides from alkenes and thiols has been carried out using Eosin Y. This is a metal-free method which uses a low catalyst loading, atmospheric oxygen as the oxidant, and visible light conditions (green light). A mechanism has been proposed that is consistent with t...

Descripción completa

Detalles Bibliográficos
Autores principales: Guerrero-Corella, Andrea, María Martinez-Gualda, Ana, Ahmadi, Fereshteh, Ming, Enrique, Fraile, Alberto, Alemán, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5779077/
https://www.ncbi.nlm.nih.gov/pubmed/28890975
http://dx.doi.org/10.1039/c7cc05672a
_version_ 1783294473037414400
author Guerrero-Corella, Andrea
María Martinez-Gualda, Ana
Ahmadi, Fereshteh
Ming, Enrique
Fraile, Alberto
Alemán, José
author_facet Guerrero-Corella, Andrea
María Martinez-Gualda, Ana
Ahmadi, Fereshteh
Ming, Enrique
Fraile, Alberto
Alemán, José
author_sort Guerrero-Corella, Andrea
collection PubMed
description The photocatalyzed synthesis of sulfoxides from alkenes and thiols has been carried out using Eosin Y. This is a metal-free method which uses a low catalyst loading, atmospheric oxygen as the oxidant, and visible light conditions (green light). A mechanism has been proposed that is consistent with the experimental results.
format Online
Article
Text
id pubmed-5779077
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-57790772018-02-15 Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides Guerrero-Corella, Andrea María Martinez-Gualda, Ana Ahmadi, Fereshteh Ming, Enrique Fraile, Alberto Alemán, José Chem Commun (Camb) Chemistry The photocatalyzed synthesis of sulfoxides from alkenes and thiols has been carried out using Eosin Y. This is a metal-free method which uses a low catalyst loading, atmospheric oxygen as the oxidant, and visible light conditions (green light). A mechanism has been proposed that is consistent with the experimental results. Royal Society of Chemistry 2017-09-25 2017-09-04 /pmc/articles/PMC5779077/ /pubmed/28890975 http://dx.doi.org/10.1039/c7cc05672a Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Guerrero-Corella, Andrea
María Martinez-Gualda, Ana
Ahmadi, Fereshteh
Ming, Enrique
Fraile, Alberto
Alemán, José
Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title_full Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title_fullStr Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title_full_unstemmed Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title_short Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
title_sort thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5779077/
https://www.ncbi.nlm.nih.gov/pubmed/28890975
http://dx.doi.org/10.1039/c7cc05672a
work_keys_str_mv AT guerrerocorellaandrea thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides
AT mariamartinezgualdaana thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides
AT ahmadifereshteh thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides
AT mingenrique thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides
AT frailealberto thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides
AT alemanjose thioleneoxidationtandemreactionundervisiblelightphotocatalysissynthesisofalkylsulfoxides

Ejemplares similares