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Energy-labeling and –read-out of reactive intermediates in solution enabled by energy-dependent reaction selectivity
Any long-lived chemical structure in solution is subject to statistical energy equilibration, so the history of any specific structure does not affect its subsequent reactions. This is not true for very short-lived intermediates, since energy equilibration takes time. Here, this idea is applied to a...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5785089/ https://www.ncbi.nlm.nih.gov/pubmed/29359761 http://dx.doi.org/10.1038/nchem.2907 |