Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System

Novel glasses in a Ga(2)S(3)-Sb(2)S(3)-AgI system were prepared with a melt-quenching method, and their glass-forming region was identified. The maximum dissolvable AgI in glasses was 65 mol%. The thermal, optical, and structural properties of glasses were investigated as a function of AgI and Ga(2)...

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Autores principales: Huang, Xinyu, Jiao, Qing, Lin, Changgui, Ma, Hongli, Zhang, Xianghua, Zhu, Erwei, Liu, Xueyun, Dai, Shixun, Xu, Tiefeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5785968/
https://www.ncbi.nlm.nih.gov/pubmed/29374280
http://dx.doi.org/10.1038/s41598-018-20144-3
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author Huang, Xinyu
Jiao, Qing
Lin, Changgui
Ma, Hongli
Zhang, Xianghua
Zhu, Erwei
Liu, Xueyun
Dai, Shixun
Xu, Tiefeng
author_facet Huang, Xinyu
Jiao, Qing
Lin, Changgui
Ma, Hongli
Zhang, Xianghua
Zhu, Erwei
Liu, Xueyun
Dai, Shixun
Xu, Tiefeng
author_sort Huang, Xinyu
collection PubMed
description Novel glasses in a Ga(2)S(3)-Sb(2)S(3)-AgI system were prepared with a melt-quenching method, and their glass-forming region was identified. The maximum dissolvable AgI in glasses was 65 mol%. The thermal, optical, and structural properties of glasses were investigated as a function of AgI and Ga(2)S(3) contents. The Ga(2)S(3)-Sb(2)S(3)-AgI glasses possess a wide region of transmission window (0.65−14 μm). An ionic conductivity of approximately 1.01 × 10(−3) S/cm can be obtained for a 40 (0.8Sb(2)S(3)-0.2Ga(2)S(3))-60AgI glass at an ambient temperature, and the ionic conductivity increased as temperature increased. The relative activation energy of Ag(+) conduction was also calculated. These novel glasses show potential for the combined application of infrared optics and solid electrolytes.
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spelling pubmed-57859682018-02-07 Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System Huang, Xinyu Jiao, Qing Lin, Changgui Ma, Hongli Zhang, Xianghua Zhu, Erwei Liu, Xueyun Dai, Shixun Xu, Tiefeng Sci Rep Article Novel glasses in a Ga(2)S(3)-Sb(2)S(3)-AgI system were prepared with a melt-quenching method, and their glass-forming region was identified. The maximum dissolvable AgI in glasses was 65 mol%. The thermal, optical, and structural properties of glasses were investigated as a function of AgI and Ga(2)S(3) contents. The Ga(2)S(3)-Sb(2)S(3)-AgI glasses possess a wide region of transmission window (0.65−14 μm). An ionic conductivity of approximately 1.01 × 10(−3) S/cm can be obtained for a 40 (0.8Sb(2)S(3)-0.2Ga(2)S(3))-60AgI glass at an ambient temperature, and the ionic conductivity increased as temperature increased. The relative activation energy of Ag(+) conduction was also calculated. These novel glasses show potential for the combined application of infrared optics and solid electrolytes. Nature Publishing Group UK 2018-01-26 /pmc/articles/PMC5785968/ /pubmed/29374280 http://dx.doi.org/10.1038/s41598-018-20144-3 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Huang, Xinyu
Jiao, Qing
Lin, Changgui
Ma, Hongli
Zhang, Xianghua
Zhu, Erwei
Liu, Xueyun
Dai, Shixun
Xu, Tiefeng
Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title_full Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title_fullStr Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title_full_unstemmed Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title_short Formation, Microstructure, and Conductivity of a Novel Ga(2)S(3)-Sb(2)S(3)-AgI Chalcogenide System
title_sort formation, microstructure, and conductivity of a novel ga(2)s(3)-sb(2)s(3)-agi chalcogenide system
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5785968/
https://www.ncbi.nlm.nih.gov/pubmed/29374280
http://dx.doi.org/10.1038/s41598-018-20144-3
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