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Integrated circuits based on conjugated polymer monolayer

It is still a great challenge to fabricate conjugated polymer monolayer field-effect transistors (PoM-FETs) due to intricate crystallization and film formation of conjugated polymers. Here we demonstrate PoM-FETs based on a single monolayer of a conjugated polymer. The resulting PoM-FETs are highly...

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Autores principales: Li, Mengmeng, Mangalore, Deepthi Kamath, Zhao, Jingbo, Carpenter, Joshua H., Yan, Hongping, Ade, Harald, Yan, He, Müllen, Klaus, Blom, Paul W. M., Pisula, Wojciech, de Leeuw, Dago M., Asadi, Kamal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792516/
https://www.ncbi.nlm.nih.gov/pubmed/29386502
http://dx.doi.org/10.1038/s41467-017-02805-5
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author Li, Mengmeng
Mangalore, Deepthi Kamath
Zhao, Jingbo
Carpenter, Joshua H.
Yan, Hongping
Ade, Harald
Yan, He
Müllen, Klaus
Blom, Paul W. M.
Pisula, Wojciech
de Leeuw, Dago M.
Asadi, Kamal
author_facet Li, Mengmeng
Mangalore, Deepthi Kamath
Zhao, Jingbo
Carpenter, Joshua H.
Yan, Hongping
Ade, Harald
Yan, He
Müllen, Klaus
Blom, Paul W. M.
Pisula, Wojciech
de Leeuw, Dago M.
Asadi, Kamal
author_sort Li, Mengmeng
collection PubMed
description It is still a great challenge to fabricate conjugated polymer monolayer field-effect transistors (PoM-FETs) due to intricate crystallization and film formation of conjugated polymers. Here we demonstrate PoM-FETs based on a single monolayer of a conjugated polymer. The resulting PoM-FETs are highly reproducible and exhibit charge carrier mobilities reaching 3 cm(2) V(−1) s(−1). The high performance is attributed to the strong interactions of the polymer chains present already in solution leading to pronounced edge-on packing and well-defined microstructure in the monolayer. The high reproducibility enables the integration of discrete unipolar PoM-FETs into inverters and ring oscillators. Real logic functionality has been demonstrated by constructing a 15-bit code generator in which hundreds of self-assembled PoM-FETs are addressed simultaneously. Our results provide the state-of-the-art example of integrated circuits based on a conjugated polymer monolayer, opening prospective pathways for bottom-up organic electronics.
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spelling pubmed-57925162018-02-02 Integrated circuits based on conjugated polymer monolayer Li, Mengmeng Mangalore, Deepthi Kamath Zhao, Jingbo Carpenter, Joshua H. Yan, Hongping Ade, Harald Yan, He Müllen, Klaus Blom, Paul W. M. Pisula, Wojciech de Leeuw, Dago M. Asadi, Kamal Nat Commun Article It is still a great challenge to fabricate conjugated polymer monolayer field-effect transistors (PoM-FETs) due to intricate crystallization and film formation of conjugated polymers. Here we demonstrate PoM-FETs based on a single monolayer of a conjugated polymer. The resulting PoM-FETs are highly reproducible and exhibit charge carrier mobilities reaching 3 cm(2) V(−1) s(−1). The high performance is attributed to the strong interactions of the polymer chains present already in solution leading to pronounced edge-on packing and well-defined microstructure in the monolayer. The high reproducibility enables the integration of discrete unipolar PoM-FETs into inverters and ring oscillators. Real logic functionality has been demonstrated by constructing a 15-bit code generator in which hundreds of self-assembled PoM-FETs are addressed simultaneously. Our results provide the state-of-the-art example of integrated circuits based on a conjugated polymer monolayer, opening prospective pathways for bottom-up organic electronics. Nature Publishing Group UK 2018-01-31 /pmc/articles/PMC5792516/ /pubmed/29386502 http://dx.doi.org/10.1038/s41467-017-02805-5 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Li, Mengmeng
Mangalore, Deepthi Kamath
Zhao, Jingbo
Carpenter, Joshua H.
Yan, Hongping
Ade, Harald
Yan, He
Müllen, Klaus
Blom, Paul W. M.
Pisula, Wojciech
de Leeuw, Dago M.
Asadi, Kamal
Integrated circuits based on conjugated polymer monolayer
title Integrated circuits based on conjugated polymer monolayer
title_full Integrated circuits based on conjugated polymer monolayer
title_fullStr Integrated circuits based on conjugated polymer monolayer
title_full_unstemmed Integrated circuits based on conjugated polymer monolayer
title_short Integrated circuits based on conjugated polymer monolayer
title_sort integrated circuits based on conjugated polymer monolayer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792516/
https://www.ncbi.nlm.nih.gov/pubmed/29386502
http://dx.doi.org/10.1038/s41467-017-02805-5
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