Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether

Evidence of ferroelasticity in a non-planar organic molecular crystal is presented for 4,4′-dicarboxydiphenyl ether. Ferroelasticity has been demonstrated by the micro- and macroscopic mechanical characterization of single crystals, including recording of a full hysteretic stress–strain cycle. The u...

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Autores principales: Engel, Emile R., Takasaki, Yuichi, Mir, Sajjad H., Takamizawa, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792905/
https://www.ncbi.nlm.nih.gov/pubmed/29410828
http://dx.doi.org/10.1098/rsos.171146
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author Engel, Emile R.
Takasaki, Yuichi
Mir, Sajjad H.
Takamizawa, Satoshi
author_facet Engel, Emile R.
Takasaki, Yuichi
Mir, Sajjad H.
Takamizawa, Satoshi
author_sort Engel, Emile R.
collection PubMed
description Evidence of ferroelasticity in a non-planar organic molecular crystal is presented for 4,4′-dicarboxydiphenyl ether. Ferroelasticity has been demonstrated by the micro- and macroscopic mechanical characterization of single crystals, including recording of a full hysteretic stress–strain cycle. The underlying mechanism involves the partial flipping of phenyl rings.
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spelling pubmed-57929052018-02-06 Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether Engel, Emile R. Takasaki, Yuichi Mir, Sajjad H. Takamizawa, Satoshi R Soc Open Sci Chemistry Evidence of ferroelasticity in a non-planar organic molecular crystal is presented for 4,4′-dicarboxydiphenyl ether. Ferroelasticity has been demonstrated by the micro- and macroscopic mechanical characterization of single crystals, including recording of a full hysteretic stress–strain cycle. The underlying mechanism involves the partial flipping of phenyl rings. The Royal Society Publishing 2018-01-17 /pmc/articles/PMC5792905/ /pubmed/29410828 http://dx.doi.org/10.1098/rsos.171146 Text en © 2018 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Engel, Emile R.
Takasaki, Yuichi
Mir, Sajjad H.
Takamizawa, Satoshi
Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title_full Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title_fullStr Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title_full_unstemmed Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title_short Twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
title_sort twinning ferroelasticity facilitated by the partial flipping of phenyl rings in single crystals of 4,4′-dicarboxydiphenyl ether
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792905/
https://www.ncbi.nlm.nih.gov/pubmed/29410828
http://dx.doi.org/10.1098/rsos.171146
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