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Analogies between Vanadoborates and Planar Aromatic Hydrocarbons: A High-Spin Analogue of Aromaticity
The vanadium-vanadium interactions in the polygonal aggregates of d(1) vanadium(IV) atoms, with a total of 4k + 2 vanadium electrons (k an integer) imbedded in an electronically inactive borate matrix in certain vanadoborate structures are analogous to the ring carbon-carbon interactions in diamagne...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5793513/ https://www.ncbi.nlm.nih.gov/pubmed/29295480 http://dx.doi.org/10.3390/ma11010015 |