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Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate
The reaction of [α-P(2)W(15)O(56)](12−) with Mn(II) and Dy(III) in an aqueous basic solution led to the isolation of an all inorganic heterometallic aggregate Na(10)(OH(2))(42)[{Dy(H(2)O)(6)}(2)Mn(4)P(4)W(30)O(112)(H(2)O)(2)]·17H(2)O (Dy(2)Mn(4)-P(2)W(15)). Single-crystal X-ray diffraction revealed...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5793653/ https://www.ncbi.nlm.nih.gov/pubmed/29342122 http://dx.doi.org/10.3390/ma11010155 |