Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes

Mesoporous nitrogen-doped silicon carbide catalysts with integrated cobalt nanoparticles (Co@N-SiC) were synthesized by the thermal decomposition of a microphase-separated block copolymer of polycarbosilane and polyethylene. The catalysts are highly active, reusable and offer selective hydrogenation...

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Detalles Bibliográficos
Autores principales: Eckardt, Mirco, Zaheer, Muhammad, Kempe, Rhett
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5803264/
https://www.ncbi.nlm.nih.gov/pubmed/29416097
http://dx.doi.org/10.1038/s41598-018-20976-z
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author Eckardt, Mirco
Zaheer, Muhammad
Kempe, Rhett
author_facet Eckardt, Mirco
Zaheer, Muhammad
Kempe, Rhett
author_sort Eckardt, Mirco
collection PubMed
description Mesoporous nitrogen-doped silicon carbide catalysts with integrated cobalt nanoparticles (Co@N-SiC) were synthesized by the thermal decomposition of a microphase-separated block copolymer of polycarbosilane and polyethylene. The catalysts are highly active, reusable and offer selective hydrogenation of the nitro group in the presence of hydrogenation-sensitive functional groups.
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spelling pubmed-58032642018-02-16 Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes Eckardt, Mirco Zaheer, Muhammad Kempe, Rhett Sci Rep Article Mesoporous nitrogen-doped silicon carbide catalysts with integrated cobalt nanoparticles (Co@N-SiC) were synthesized by the thermal decomposition of a microphase-separated block copolymer of polycarbosilane and polyethylene. The catalysts are highly active, reusable and offer selective hydrogenation of the nitro group in the presence of hydrogenation-sensitive functional groups. Nature Publishing Group UK 2018-02-07 /pmc/articles/PMC5803264/ /pubmed/29416097 http://dx.doi.org/10.1038/s41598-018-20976-z Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Eckardt, Mirco
Zaheer, Muhammad
Kempe, Rhett
Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title_full Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title_fullStr Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title_full_unstemmed Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title_short Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
title_sort nitrogen-doped mesoporous sic materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5803264/
https://www.ncbi.nlm.nih.gov/pubmed/29416097
http://dx.doi.org/10.1038/s41598-018-20976-z
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AT kemperhett nitrogendopedmesoporoussicmaterialswithcatalyticallyactivecobaltnanoparticlesfortheefficientandselectivehydrogenationofnitroarenes

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