Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(iii)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in...

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Autores principales: Lu, Yi, Wang, Huai-Wei, Spangler, Jillian E., Chen, Kai, Cui, Pei-Pei, Zhao, Yue, Sun, Wei-Yin, Yu, Jin-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810239/
https://www.ncbi.nlm.nih.gov/pubmed/29449919
http://dx.doi.org/10.1039/c4sc03350g
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author Lu, Yi
Wang, Huai-Wei
Spangler, Jillian E.
Chen, Kai
Cui, Pei-Pei
Zhao, Yue
Sun, Wei-Yin
Yu, Jin-Quan
author_facet Lu, Yi
Wang, Huai-Wei
Spangler, Jillian E.
Chen, Kai
Cui, Pei-Pei
Zhao, Yue
Sun, Wei-Yin
Yu, Jin-Quan
author_sort Lu, Yi
collection PubMed
description The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(iii)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant.
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spelling pubmed-58102392018-02-15 Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant Lu, Yi Wang, Huai-Wei Spangler, Jillian E. Chen, Kai Cui, Pei-Pei Zhao, Yue Sun, Wei-Yin Yu, Jin-Quan Chem Sci Chemistry The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(iii)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in the presence of air as the sole oxidant without using a co-oxidant. Royal Society of Chemistry 2015-03-01 2015-01-08 /pmc/articles/PMC5810239/ /pubmed/29449919 http://dx.doi.org/10.1039/c4sc03350g Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Lu, Yi
Wang, Huai-Wei
Spangler, Jillian E.
Chen, Kai
Cui, Pei-Pei
Zhao, Yue
Sun, Wei-Yin
Yu, Jin-Quan
Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title_full Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title_fullStr Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title_full_unstemmed Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title_short Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
title_sort rh(iii)-catalyzed c–h olefination of n-pentafluoroaryl benzamides using air as the sole oxidant
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810239/
https://www.ncbi.nlm.nih.gov/pubmed/29449919
http://dx.doi.org/10.1039/c4sc03350g
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