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Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a rhodium(iii)-catalyzed C–H activation reaction. The use of an N-pentafluorophenyl benzamide directing group is crucial for achieving catalytic turnovers in...

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Detalles Bibliográficos
Autores principales: Lu, Yi, Wang, Huai-Wei, Spangler, Jillian E., Chen, Kai, Cui, Pei-Pei, Zhao, Yue, Sun, Wei-Yin, Yu, Jin-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810239/
https://www.ncbi.nlm.nih.gov/pubmed/29449919
http://dx.doi.org/10.1039/c4sc03350g