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A comprehensive test set of epoxidation rate constants for iron(iv)–oxo porphyrin cation radical complexes

Cytochrome P450 enzymes are heme based monoxygenases that catalyse a range of oxygen atom transfer reactions with various substrates, including aliphatic and aromatic hydroxylation as well as epoxidation reactions. The active species is short-lived and difficult to trap and characterize experimental...

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Detalles Bibliográficos
Autores principales: Sainna, Mala A., Kumar, Suresh, Kumar, Devesh, Fornarini, Simonetta, Crestoni, Maria Elisa, de Visser, Sam P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811088/
https://www.ncbi.nlm.nih.gov/pubmed/29560240
http://dx.doi.org/10.1039/c4sc02717e