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A comprehensive test set of epoxidation rate constants for iron(iv)–oxo porphyrin cation radical complexes
Cytochrome P450 enzymes are heme based monoxygenases that catalyse a range of oxygen atom transfer reactions with various substrates, including aliphatic and aromatic hydroxylation as well as epoxidation reactions. The active species is short-lived and difficult to trap and characterize experimental...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811088/ https://www.ncbi.nlm.nih.gov/pubmed/29560240 http://dx.doi.org/10.1039/c4sc02717e |