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Carbo-cyclohexadienes vs. carbo-benzenes: structure and conjugative properties

Ideally C (s)-/C (2v)-symmetric chromophores, constituted by two electro-active groups conjugated through the carbo-mer of the cyclohexa-1,3-diene core, are selectively prepared by the SnCl(2)-mediated reduction of tailored hexaoxy-[6]pericyclynes: in the latter substrates, one of the 1,4-dioxybut-2...

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Detalles Bibliográficos
Autores principales: Rives, Arnaud, Baglai, Iaroslav, Barthes, Cécile, Maraval, Valérie, Saffon-Merceron, Nathalie, Saquet, Alix, Voitenko, Zoia, Volovenko, Yulian, Chauvin, Remi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811109/
https://www.ncbi.nlm.nih.gov/pubmed/29560201
http://dx.doi.org/10.1039/c4sc02742f