Cargando…

A counteranion triggered arylation strategy using diaryliodonium fluorides

A mild and transition metal-free counteranion triggered arylation strategy has been developed using diaryliodonium fluorides. The fluoride counteranion within the hypervalent iodonium species displays unusual reactivity that activates a phenolic O–H bond leading to electrophilic O-arylation. A wide...

Descripción completa

Detalles Bibliográficos
Autores principales:	Chan, L., McNally, A., Toh, Q. Y., Mendoza, A., Gaunt, M. J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811167/ https://www.ncbi.nlm.nih.gov/pubmed/29541441 http://dx.doi.org/10.1039/c4sc02856b

Ejemplares similares

Ligand and counteranion enabled regiodivergent C–H bond functionalization of naphthols with α-aryl-α-diazoesters
por: Yu, Zhunzhun, et al.
Publicado: (2019)

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts
por: Cahard, Elise, et al.
Publicado: (2015)

The Diaryliodonium(III) Salts Reaction With Free-Radicals Enables One-Pot Double Arylation of Naphthols
por: Satkar, Yuvraj, et al.
Publicado: (2020)

Arylation with Unsymmetrical Diaryliodonium Salts: A Chemoselectivity Study
por: Malmgren, Joel, et al.
Publicado: (2013)

Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines
por: Beaud, Rodolphe, et al.
Publicado: (2016)

Competing Pathways in O‐Arylations with Diaryliodonium Salts: Mechanistic Insights
por: Stridfeldt, Elin, et al.
Publicado: (2017)

Cu-catalyzed N-3-Arylation of Hydantoins Using Diaryliodonium Salts
por: Neerbye Berntsen, Linn, et al.
Publicado: (2020)

Palladium-catalyzed direct β-arylation of ketones with diaryliodonium salts: a stoichiometric heavy metal-free and user-friendly approach
por: Huang, Zhongxing, et al.
Publicado: (2015)

N- and O-arylation of pyridin-2-ones with diaryliodonium salts: base-dependent orthogonal selectivity under metal-free conditions
por: Kuriyama, Masami, et al.
Publicado: (2020)

Impact of counteranions on N-heterocyclic carbene gold(i)-catalyzed cyclization of propargylic amide
por: Ali, Hafiz Saqib, et al.
Publicado: (2023)

Metal-Free S-Arylation of Phosphorothioate Diesters and Related Compounds with Diaryliodonium Salts
por: Sarkar, Sudeep, et al.
Publicado: (2023)

β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp3)–H bonds using a palladium catalyst
por: Peng, Jing, et al.
Publicado: (2016)

Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
por: Omann, Lukas, et al.
Publicado: (2018)

Late-stage modification of peptides and proteins at cysteine with diaryliodonium salts
por: Byrne, Stephen A., et al.
Publicado: (2021)

N 1-Arylation of 1,4-Benzodiazepine-2-ones with Diaryliodonium Salts
por: Khan, Raysa, et al.
Publicado: (2018)

Transition Metal‐Free N‐Arylation of Amino Acid Esters with Diaryliodonium Salts
por: Kervefors, Gabriella, et al.
Publicado: (2021)

Copper-Catalyzed Synthesis of Axially Chiral Biaryls with Diaryliodonium Salts as Arylation Reagents
por: Zhang, Ji-Wei, et al.
Publicado: (2021)

Palladium-catalyzed synthesis of N-arylated carbazoles using anilines and cyclic diaryliodonium salts
por: Riedmüller, Stefan, et al.
Publicado: (2013)

Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts
por: Sallio, Romain, et al.
Publicado: (2021)

Diaryliodonium salts facilitate metal-free mechanoredox free radical polymerizations
por: Zeitler, Sarah M., et al.
Publicado: (2022)

Facile One‐Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone
por: Soldatova, Natalia, et al.
Publicado: (2016)

Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
por: Ye, Lianbao, et al.
Publicado: (2019)

One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
por: Soldatova, Natalia, et al.
Publicado: (2018)

DFT calculations on the mechanism of copper-catalysed tandem arylation–cyclisation reactions of alkynes and diaryliodonium salts
por: Stenczel, Tamás Károly, et al.
Publicado: (2018)

Metal‐Free and Open‐Air Arylation Reactions of Diaryliodonium Salts for DNA‐Encoded Library Synthesis
por: Xu, Hongtao, et al.
Publicado: (2022)

Wet carbonate-promoted radical arylation of vinyl pinacolboronates with diaryliodonium salts yields substituted olefins
por: Wu, Chao, et al.
Publicado: (2020)

Silylboronate-Mediated Defluorosilylation of Aryl Fluorides with or without Ni-Catalyst
por: Zhou, Jun, et al.
Publicado: (2021)

Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion
por: Wu, Qian, et al.
Publicado: (2020)

Flow Synthesis of Diaryliodonium Triflates
por: Laudadio, Gabriele, et al.
Publicado: (2017)

High ionic conduction, toughness and self-healing poly(ionic liquid)-based electrolytes enabled by synergy between flexible units and counteranions
por: Yang, Fu Jie, et al.
Publicado: (2021)

One-pot palladium-catalyzed synthesis of sulfonyl fluorides from aryl bromides
por: Davies, Alyn T., et al.
Publicado: (2017)

Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes
por: Zhou, Jun, et al.
Publicado: (2023)

Recent Advances in Transition-Metal-Free Late-Stage C-H and N-H Arylation of Heteroarenes Using Diaryliodonium Salts
por: Besson, Thierry, et al.
Publicado: (2021)

Aryl fluoride functionalized graphene oxides for excellent room temperature ammonia sensitivity/selectivity
por: Khurshid, Farheen, et al.
Publicado: (2018)

A regio- and stereoselective Heck–Matsuda process for construction of γ-aryl allylsulfonyl fluorides
por: Qin, Hao-Yong, et al.
Publicado: (2022)

Asymmetric counteranion-directed Lewis acid organocatalysis for the scalable cyanosilylation of aldehydes
por: Zhang, Zhipeng, et al.
Publicado: (2016)

Counteranions in the Stimulation Solution Alter the Dynamics of Exocytosis Consistent with the Hofmeister Series
por: He, Xiulan, et al.
Publicado: (2020)

Counteranions at Peripheral Sites Tune Guest Affinity for a Protonated Hemicryptophane
por: Lin, Yannan, et al.
Publicado: (2022)

Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination
por: Yuan, Kedong, et al.
Publicado: (2020)

Synthesis of (18)F-difluoromethylarenes using aryl boronic acids, ethyl bromofluoroacetate and [(18)F]fluoride
por: Sap, Jeroen B. I., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_ilrgpdeom9hjj0ji3820rtieh3