A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate

The homopolymerization and copolymerization of styrene and methyl methacrylate, initiated for the first time by the combination of azo-bis-isobutyronitrile (AIBN) with [(SiMes)Ru(PPh(3))(Ind)Cl(2)] complex. The reactions were successfully carried out, on a large scale, in presence this complex at 80...

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Autores principales: Al-Majid, Abdullah M., Shamsan, Waseem Sharaf, Al-Odayn, Abdel-Basit Mohammed, Nahra, Fady, Aouak, Taieb, Nolan, Steven P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2016
Materias:
Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5812117/
https://www.ncbi.nlm.nih.gov/pubmed/29491790
http://dx.doi.org/10.1080/15685551.2016.1231049
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author Al-Majid, Abdullah M.
Shamsan, Waseem Sharaf
Al-Odayn, Abdel-Basit Mohammed
Nahra, Fady
Aouak, Taieb
Nolan, Steven P.
author_facet Al-Majid, Abdullah M.
Shamsan, Waseem Sharaf
Al-Odayn, Abdel-Basit Mohammed
Nahra, Fady
Aouak, Taieb
Nolan, Steven P.
author_sort Al-Majid, Abdullah M.
collection PubMed
description The homopolymerization and copolymerization of styrene and methyl methacrylate, initiated for the first time by the combination of azo-bis-isobutyronitrile (AIBN) with [(SiMes)Ru(PPh(3))(Ind)Cl(2)] complex. The reactions were successfully carried out, on a large scale, in presence this complex at 80 °C. It was concluded from the data obtained that the association of AIBN with the ruthenium complex reduces considerably the transfer reactions and leads to the controlled radical polymerization and the well-defined polymers.
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spelling pubmed-58121172018-02-28 A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate Al-Majid, Abdullah M. Shamsan, Waseem Sharaf Al-Odayn, Abdel-Basit Mohammed Nahra, Fady Aouak, Taieb Nolan, Steven P. Des Monomers Polym Articles The homopolymerization and copolymerization of styrene and methyl methacrylate, initiated for the first time by the combination of azo-bis-isobutyronitrile (AIBN) with [(SiMes)Ru(PPh(3))(Ind)Cl(2)] complex. The reactions were successfully carried out, on a large scale, in presence this complex at 80 °C. It was concluded from the data obtained that the association of AIBN with the ruthenium complex reduces considerably the transfer reactions and leads to the controlled radical polymerization and the well-defined polymers. Taylor & Francis 2016-10-21 /pmc/articles/PMC5812117/ /pubmed/29491790 http://dx.doi.org/10.1080/15685551.2016.1231049 Text en © 2016 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group http://creativecommons.org/licenses/by/4.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Articles
Al-Majid, Abdullah M.
Shamsan, Waseem Sharaf
Al-Odayn, Abdel-Basit Mohammed
Nahra, Fady
Aouak, Taieb
Nolan, Steven P.
A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title_full A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title_fullStr A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title_full_unstemmed A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title_short A new initiating system based on [(SiMes)Ru(PPh(3))(Ind)Cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
title_sort new initiating system based on [(simes)ru(pph(3))(ind)cl(2)] combined with azo-bis-isobutyronitrile in the polymerization and copolymerization of styrene and methyl methacrylate
topic Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5812117/
https://www.ncbi.nlm.nih.gov/pubmed/29491790
http://dx.doi.org/10.1080/15685551.2016.1231049
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