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Isomerisation of nido-[C(2)B(10)H(12)](2–) dianions: unprecedented rearrangements and new structural motifs in carborane cluster chemistry
Dianionic nido-[C(2)B(10)](2–) species are key intermediates in the polyhedral expansion from 12- to 13-vertex carboranes and metallacarboranes, and the isomer adopted by these nido intermediates dictates the isomeric form of the 13-vertex product. Upon reduction and metallation of para-carborane up...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5812468/ https://www.ncbi.nlm.nih.gov/pubmed/29560248 http://dx.doi.org/10.1039/c5sc00726g |